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Ultraviolet

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Ultraviolet ( UV ) is a form of electromagnetic radiation with wavelength from 10 (with a corresponding frequency around 30 PHz) to 400 nm (750 THz), shorter than that of visible light, but longer than X-rays. UV radiation is present in sunlight, and constitutes about 10% of the total electromagnetic radiation output from the Sun. It is also produced by electric arcs and specialized lights, such as mercury-vapor lamps, tanning lamps, and black lights. Although long-wavelength ultraviolet is not considered an ionizing radiation because its photons lack the energy to ionize atoms, it can cause chemical reactions and causes many substances to glow or fluoresce. Consequently, the chemical and biological effects of UV are greater than simple heating effects, and many practical applications of UV radiation derive from its interactions with organic molecules. It can also damage skin and/or give a painful sunburn. Short-wave ultraviolet light damages DNA and sterilizes surfaces with which it

Visibility

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Ultraviolet rays are invisible to most humans. The lens of the human eye blocks most radiation in the wavelength range of 300–400 nm; shorter wavelengths are blocked by the cornea. Humans also lack color receptor adaptations for ultraviolet rays. Nevertheless, the photoreceptors of the retina are sensitive to near-UV, and people lacking a lens (a condition known as aphakia) perceive near-UV as whitish-blue or whitish-violet. Under some conditions, children and young adults can see ultraviolet down to wavelengths around 310 nm. Near-UV radiation is visible to insects, some mammals, and birds. Small birds have a fourth color receptor for ultraviolet rays; this gives birds "true" UV vision.

Discovery

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"Ultraviolet" means "beyond violet" (from Latin ultra , "beyond"), violet being the color of the highest frequencies of visible light. Ultraviolet has a higher frequency (thus a shorter wavelength) than violet light. UV radiation was discovered in 1801 when the German physicist Johann Wilhelm Ritter observed that invisible rays just beyond the violet end of the visible spectrum darkened silver chloride-soaked paper more quickly than violet light itself. He called them "(de-)oxidizing rays" (German: de-oxidierende Strahlen ) to emphasize chemical reactivity and to distinguish them from "heat rays", discovered the previous year at the other end of the visible spectrum. The simpler term "chemical rays" was adopted soon afterwards, and remained popular throughout the 19th century, although some said that this radiation was entirely different from light (notably John William Draper, who named them "tithonic rays"). The te

Subtypes

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The electromagnetic spectrum of ultraviolet radiation (UVR), defined most broadly as 10–400 nanometers, can be subdivided into a number of ranges recommended by the ISO standard ISO-21348: Name Abbreviation Wavelength (nm) Photon energy (eV, aJ) Notes/alternative names Ultraviolet C UVC 100–280 4.43–12.4, 0.710–1.987 Short-wave, germicidal, completely absorbed by the ozone layer and atmosphere: hard UV. Ultraviolet B UVB 280–315 3.94–4.43, 0.631–0.710 Medium-wave, mostly absorbed by the ozone layer: intermediate UV; Dorno  de radiation. Ultraviolet A UVA 315–400 3.10–3.94, 0.497–0.631 Long-wave, black light, not absorbed by the ozone layer: soft UV. Hydrogen Lyman-alpha H Lyman-α 121–122 10.16–10.25, 1.628–1.642 Spectral line at 121.6 nm, 10.20   eV. Ionizing radiation at shorter wavelengths. Far ultraviolet FUV 122–200 6.20–10.16, 0.993–1.628 Middle ultraviolet MUV 200–300 4.13–6.20, 0.662–0.993 Near ultraviolet NUV 300–400 3.10–4.1

Solar ultraviolet

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Very hot objects emit UV radiation (see black-body radiation). The Sun emits ultraviolet radiation at all wavelengths, including the extreme ultraviolet where it crosses into X-rays at 10 nm. Extremely hot stars emit proportionally more UV radiation than the Sun. Sunlight in space at the top of Earth's atmosphere (see solar constant) is composed of about 50% infrared light, 40% visible light, and 10% ultraviolet light, for a total intensity of about 1400 W/m2 in vacuum. The atmosphere blocks about 77% of the Sun's UV, when the Sun is highest in the sky (at zenith), with absorption increasing at shorter UV wavelengths. At ground level with the sun at zenith, sunlight is 44% visible light, 3% ultraviolet, and the remainder infrared. Of the ultraviolet radiation that reaches the Earth's surface, more than 95% is the longer wavelengths of UVA, with the small remainder UVB. Almost no UVC reaches the Earth's surface. The fraction of UVB which remains in UV radiation after pas

Blockers, absorbers, and windows

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Ultraviolet absorbers are molecules used in organic materials (polymers, paints, etc.) to absorb UV radiation to reduce the UV degradation (photo-oxidation) of a material. The absorbers can themselves degrade over time, so monitoring of absorber levels in weathered materials is necessary. In sunscreen, ingredients that absorb UVA/UVB rays, such as avobenzone, oxybenzone and octyl methoxycinnamate, are organic chemical absorbers or "blockers". They are contrasted with inorganic absorbers/"blockers" of UV radiation such as carbon black, titanium dioxide, and zinc oxide. For clothing, the ultraviolet protection factor (UPF) represents the ratio of sunburn-causing UV without and with the protection of the fabric, similar to sun protection factor (SPF) ratings for sunscreen. citation needed Standard summer fabrics have UPFs around 6, which means that about 20% of UV will pass through. citation needed Suspended nanoparticles in stained glass prevent UV rays from causing

Artificial sources

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"Black lights" edit A black light lamp emits long-wave UVA radiation and little visible light. Fluorescent black light lamps work similarly to other fluorescent lamps, but use a phosphor on the inner tube surface which emits UVA radiation instead of visible light. Some lamps use a deep-bluish-purple Wood's glass optical filter that blocks almost all visible light with wavelengths longer than 400 nanometres. Others use plain glass instead of the more expensive Wood's glass, so they appear light-blue to the eye when operating. Incandescent black lights are also produced, using a filter coating on the envelope of an incandescent bulb that absorbs visible light ( see section below ). These are cheaper but very inefficient, emitting only a fraction of a percent of their power as UV. Mercury-vapor black lights in ratings up to 1 kW with UV-emitting phosphor and an envelope of Wood's glass are used for theatrical and concert displays. Black lights are used in applicatio

Human health-related effects

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The impact of ultraviolet radiation on human health has implications for the risks and benefits of sun exposure and is also implicated in issues such as fluorescent lamps and health. Getting too much sun exposure can be harmful, but in moderation, sun exposure is beneficial. Beneficial effects edit UV light (specifically, UVB) causes the body to produce vitamin D, which is essential for life. Humans need some UV radiation to maintain adequate vitamin D levels. According to the World Health Organization There is no doubt that a little sunlight is good for you! But 5 to 15 minutes of casual sun exposure of hands, face and arms two to three times a week during the summer months is sufficient to keep your vitamin D levels high. Vitamin D can also be obtained from food and supplementation. Excess sun exposure produces harmful effects, however. Vitamin D promotes the creation of serotonin. The production of serotonin is in direct proportion to the degree of bright sunlight the body receives.

Degradation of polymers, pigments and dyes

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UV degradation is one form of polymer degradation that affects plastics exposed to sunlight. The problem appears as discoloration or fading, cracking, loss of strength or disintegration. The effects of attack increase with exposure time and sunlight intensity. The addition of UV absorbers inhibits the effect. Sensitive polymers include thermoplastics and speciality fibers like aramids. UV absorption leads to chain degradation and loss of strength at sensitive points in the chain structure. Aramid rope must be shielded with a sheath of thermoplastic if it is to retain its strength. Many pigments and dyes absorb UV and change colour, so paintings and textiles may need extra protection both from sunlight and fluorescent bulbs, two common sources of UV radiation. Window glass absorbs some harmful UV, but valuable artifacts need extra shielding. Many museums place black curtains over watercolour paintings and ancient textiles, for example. Since watercolours can have very low pigment levels

Applications

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Because of its ability to cause chemical reactions and excite fluorescence in materials, ultraviolet radiation has a number of applications. The following table gives some uses of specific wavelength bands in the UV spectrum 13.5 nm : Extreme ultraviolet lithography 30–200 nm : Photoionization, ultraviolet photoelectron spectroscopy, standard integrated circuit manufacture by photolithography 230–365 nm : UV-ID, label tracking, barcodes 230–400 nm : Optical sensors, various instrumentation 240–280 nm : Disinfection, decontamination of surfaces and water (DNA absorption has a peak at 260 nm), germicidal lamps 200–400 nm : Forensic analysis, drug detection 270–360 nm : Protein analysis, DNA sequencing, drug discovery 280–400 nm : Medical imaging of cells 300–320 nm : Light therapy in medicine 300–365 nm : Curing of polymers and printer inks 350–370 nm : Bug zappers (flies are most attracted to light at 365 nm) Photography edit Photographic film responds to ultraviolet radiation

Evolutionary significance

The evolution of early reproductive proteins and enzymes is attributed in modern models of evolutionary theory to ultraviolet radiation. UVB causes thymine base pairs next to each other in genetic sequences to bond together into thymine dimers, a disruption in the strand that reproductive enzymes cannot copy. This leads to frameshifting during genetic replication and protein synthesis, usually killing the cell. Before formation of the UV-blocking ozone layer, when early prokaryotes approached the surface of the ocean, they almost invariably died out. The few that survived had developed enzymes that monitored the genetic material and removed thymine dimers by nucleotide excision repair enzymes. Many enzymes and proteins involved in modern mitosis and meiosis are similar to repair enzymes, and are believed to be evolved modifications of the enzymes originally used to overcome DNA damages caused by UV.

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